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Stress concentration in materials is a common issue in various load-bearing structures as it is linked to a potential mechanical failure. Thus, unnecessary cut-outs or contaminating inclusions are typically to be avoided, as externally applied forces will (re)distribute around the obstacles, reaching potentially critically high stress values at their edges [23]. For instance, formerly square-shaped airplane windows, which have caused fatal accidents by crack initiation at the corners, crack propagation, and eventually fatigue of the fuselage [24], are now generally of oval shape. In some cases, however, certain geometries acting as stress concentrators are built in devices by purpose, e.g., v-shaped cuts in tear-open packages, or are researched to create aligned surface patterns [25], to grow nanowires [26], or to fabricate master molds for nanofluidics [27]. These examples indicate that stress concentration, if implemented in the design of devices, may allow for realizing distinct device functions.


Based on our hypothesis, cavities introduced into a polymeric substrate such as an elastic polymer film can be of different geometrical shapes, depths, and orientations relative to an anticipated stretching direction. Therefore, if properly selected and combined, these cut-outs can be assumed to show different extents of stress concentration, eventually resulting in different local strains upon exposure to an external stretching force. The cut-outs can also serve as containers for substances, with different substances being loaded in cut-outs of different geometries in particular, and may be sealed by a brittle coating material. In this way, according to our concept, a stretching deformation applied to the elastic polymer substrate should allow a geometry-dependent consecutive opening of sealed containers for an on-demand release of different substances from the same device.


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